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Author(s):   Hitsuda, K.; Takahashi, K.; Matsumi, Y.; Wallington
Title:   Kinetics of the Reactions of Cl(3P1/2) and Cl(2P3/2) Atoms with C2H6, C2D6, CH3F, and CH3CF3 at 298 K
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   5131 - 5136
Year:   2001
Reference type:   Journal article
Squib:   2001HIT/TAK5131-5136

Reaction:   Cl(2P1/2) + CF4 → Cl(2P3/2) + CF4
Reaction order:   2
Temperature:   298 K
Pressure:  3.07E-4 bar
Rate expression:   2.3x10-11 [±4.0x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Temperature at which these experiments is not reported and is presumed to be approximately 298 K.

Cl(2P1/2) and Cl(2P3/2) were monitored using vacuum ultraviolet laser induced fuorescence (VUV-LIF).

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