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Title: Kinetics of the Reactions of Cl(3P1/2) and Cl(2P3/2) Atoms with C2H6, C2D6, CH3F, and CH3CF3 at 298 K
Journal: J. Phys. Chem. A
Volume: 105
Page(s): 5131 - 5136
Year: 2001
Reference type: Journal article
Squib: 2001HIT/TAK5131-5136
Reaction:
Cl(2P1/2) + CF4 → Cl(2P3/2) + CF4
Reaction order:
2
Temperature:
298
K
Pressure: 3.07E-4 bar
Rate expression:
2.3x10-11 [±4.0x10-12 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Temperature at which these experiments is not reported and is presumed to be approximately 298 K.
Cl(2P1/2) and Cl(2P3/2) were monitored using vacuum ultraviolet laser induced fuorescence (VUV-LIF).
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