NIST Chemical Kinetics Database

Author(s):   Lifshitz, A.; Suslensky, A.; Tamburu, C.
Title:   Thermal Reactions of Isodihydrobenzofuran: Experimental Results and Computer Modeling
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   3148 - 3157
Year:   2001
Reference type:   Journal article
Squib:   2001LIF/SUS3148-3157

Reaction:   1,3-Dihydro-2-benzofuran → Other Products + Toluene
Reaction order:   1
Temperature:   1050 - 1300 K
Pressure:  2.50E-10 - 3.00E-10 bar
Rate expression:   1.4x10¹¹ [s^-1] e^{-207526 [J/mole]/RT}
Bath gas:   Ar
Category: Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Temperature calibration by the thermal decomposition of 1,1,1-trifluoroethane.

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
1050	6.64E0
1075	1.15E1
1100	1.96E1
1125	3.24E1
1150	5.25E1
1175	8.33E1
1200	1.30E2
1225	1.98E2
1250	2.98E2
1275	4.41E2
1300	6.42E2