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Title: Collisional Quenching and Vibrational Energy Transfer in the Electronis State of the CF Radical
Journal: J. Phys. Chem. A
Volume: 105
Page(s): 29 - 33
Year: 2001
Reference type: Journal article
Squib: 2001NIZ/DAG29-33
Reaction:
CF (A 2Sigma+, v=1) + CF4 → CF4 + CF
Reaction order:
2
Temperature:
298
K
Pressure: 4.00E-4 - 2.67E-2 bar
Rate expression:
4.0x10-12 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Experiments conducted at "room temperature"; 298 K presumed.
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