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Author(s):   Avzianova, E.V.; Ariya, P.A.
Title:   Temperature-Dependent Kinetic Study for Ozonolysis of Selected Tropospheric Alkenes
Journal:   Int J. Chem. Kinet.
Page(s):   678 - 684
Year:   2002
Reference type:   Journal article
Squib:   2002AVZ/ARI678-684

Reaction:   CH2=CCl2 + O3 → Products
Reaction order:   2
Reference reaction:   n-C6H14 + O3 → Products
Temperature:   278 - 353 K
Pressure:  1.01 bar
Rate expression:   4.6x10-14 [cm3/molecule s] e-38526 [±1167 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Other
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
278 2.65E-21
300 9.01E-21
325 2.96E-20
350 8.19E-20
353 9.16E-20