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Title: Kinetics of OH Radical Reactions with Methane in the Temperature Range 295-660 K and with Dimethyl Ether and Methyl-tert-butyl Ether in the Temperature Range 295-618 K
Journal: J. Phys. Chem. A
Volume: 106
Page(s): 4384 - 4389
Year: 2002
Reference type: Journal article
Squib: 2002BON/DAE4384-4389
Reaction:
tert-C4H9OCH3 + ·OH → Other Products + H2O
Reaction order:
2
Temperature:
230 - 750
K
Rate expression:
2.81x10-13 [±1.6x10-14 cm3/molecule s] (T/298 K)2.93 e5953 [±150 J/mole]/RT
Category: Review
Data type:
Experimental value and limited review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 230 | 2.95E-12 |
| 250 | 2.94E-12 |
| 300 | 3.11E-12 |
| 350 | 3.48E-12 |
| 400 | 3.98E-12 |
| 450 | 4.61E-12 |
| 500 | 5.35E-12 |
| 550 | 6.21E-12 |
| 600 | 7.19E-12 |
| 650 | 8.30E-12 |
| 700 | 9.53E-12 |
| 750 | 1.09E-11 |