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Author(s):
Chemma, S.A.; Holbrook, K.A.; Oldershaw, G.A.; Walker, R.W.
Title:
Kinetics and Mechanism Associated with the Reactions of Hydroxyl Radicals and of Chlorine Atoms with 1-Propanol under Near-Tropospheric Conditions Between 273 and 343 K
Journal:
Int J. Chem. Kinet.
Volume:
34
Page(s):
110 - 121
Year:
2002
Reference type:
Journal article
Squib:
2002CHE/HOL110-121
Reaction:
n-C3H7OH + ·OH → Products
Reaction order:
2
Temperature:
298 - 753
K
Rate expression:
1.33x10-12 [cm3/molecule s] (T/298 K)1.80 e3509 [J/mole]/RT
Category: Review
Data type:
Experimental value and limited review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
| 298 |
5.49E-12 |
| 300 |
5.51E-12 |
| 325 |
5.71E-12 |
| 350 |
5.94E-12 |
| 375 |
6.21E-12 |
| 400 |
6.50E-12 |
| 425 |
6.82E-12 |
| 450 |
7.15E-12 |
| 475 |
7.50E-12 |
| 500 |
7.87E-12 |
| 525 |
8.25E-12 |
| 550 |
8.65E-12 |
| 575 |
9.06E-12 |
| 600 |
9.49E-12 |
| 625 |
9.93E-12 |
| 650 |
1.04E-11 |
| 675 |
1.09E-11 |
| 700 |
1.13E-11 |
| 725 |
1.18E-11 |
| 750 |
1.23E-11 |
| 753 |
1.24E-11 |
|