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Accessibility information
Author(s):   Olleta, A.C.; Lane, S.I.
Title:   A Theoretical Study of Hydrogen and Chlorine Transfer Reactions from Fluorine- and Chlorine-Substituted Methanes by F3C. Radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   3341 - 3349
Year:   2002
Reference type:   Journal article
Squib:   2002OLL/LAN3341-3349

Reaction:   CCl4 + ·CF3CF3Cl + ·CCl3
Reaction order:   2
Temperature:   369 - 513 K
Rate expression:   2.4x10-12 [cm3/molecule s] e-33346 [J/mole]/RT
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
369 4.57E-17
375 5.44E-17
400 1.06E-16
425 1.91E-16
450 3.23E-16
475 5.17E-16
500 7.88E-16
513 9.66E-16