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Title: A Theoretical Study of Hydrogen and Chlorine Transfer Reactions from Fluorine- and Chlorine-Substituted Methanes by F3C. Radicals
Journal: Phys. Chem. Chem. Phys.
Volume: 4
Page(s): 3341 - 3349
Year: 2002
Reference type: Journal article
Squib: 2002OLL/LAN3341-3349
Reaction:
CHCl3 + ·CF3 → CHF3 + ·CCl3
Reaction order:
2
Temperature:
367 - 569
K
Rate expression:
1.23x10-13 [cm3/molecule s] e-27824 [J/mole]/RT
Category: Theory
Data type:
Ab initio
Pressure dependence:
Rate constant is high pressure limit
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 367 | 1.35E-17 |
| 375 | 1.64E-17 |
| 400 | 2.86E-17 |
| 425 | 4.68E-17 |
| 450 | 7.25E-17 |
| 475 | 1.07E-16 |
| 500 | 1.53E-16 |
| 525 | 2.10E-16 |
| 550 | 2.80E-16 |
| 569 | 3.44E-16 |