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Title: Kinetics of the Reactions of Fluorine and Chlorine Atoms with Ethylene Oxide (Oxirane)
Journal: Int J. Chem. Kinet.
Volume: 34
Page(s): 122 - 125
Year: 2002
Reference type: Journal article
Squib: 2002PON/HUR122-125
Reaction:
Oxirane + ·F → Products
Reaction order:
2
Reference reaction:
CH4 + ·F → ·CH3 + HF
Reference reaction order:
2
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
9.4x10-11±1.6x10-11
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In both real time and by end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Relative rate measurement, reference reactions F + CH4 -> CH3 + HF and F + C2H6 -> C2H5 + HF, 140-l Pyrex reactor / FTIR, agrees with previous work
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