Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Qian, H.-B.; Turton, D.; Seakins, P.W.; Pilling, M.J.
Title:   A Laser Flash Photolysis/IR Diode Laser Absorption Study of the Reaction of Chlorine Atoms with Selected Alkanes
Journal:   Int J. Chem. Kinet.
Volume:   34
Page(s):   86 - 94
Year:   2002
Reference type:   Journal article
Squib:   2002QIA/TUR86-94

Reaction:   n-C4H10 + Cln-C4H9 + HCl
Reaction order:   2
Temperature:   298 K
Rate expression:   1.91x10-10 [±1.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Cl from oxalyl chloride photolysis at 193 nm, IR diode laser absorption (HCl product), Herriot cell, structure activity relationship (SAR) for Cl atom abstraction reactions given, this work obtained k = 1.91(+/-0.10)E-10, but the authors recommend 2.06(+/-0.12)E-10 based on three studies

View full bibliographic record.