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Title: A Laser Flash Photolysis/IR Diode Laser Absorption Study of the Reaction of Chlorine Atoms with Selected Alkanes
Journal: Int J. Chem. Kinet.
Volume: 34
Page(s): 86 - 94
Year: 2002
Reference type: Journal article
Squib: 2002QIA/TUR86-94
Reaction:
n-C4H10 + Cl → n-C4H9 + HCl
Reaction order:
2
Temperature:
298
K
Rate expression:
1.91x10-10 [±1.0x10-11 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
IR absorption
Comments:
Cl from oxalyl chloride photolysis at 193 nm, IR diode laser absorption (HCl product), Herriot cell, structure activity relationship (SAR) for Cl atom abstraction reactions given, this work obtained k = 1.91(+/-0.10)E-10, but the authors recommend 2.06(+/-0.12)E-10 based on three studies
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