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Author(s):   Rajakumar, B.; Reddy, K.P.J.; Arunan, E.
Title:   Unimolecular HCl Elimination from 1,2-Dichloroethane: A Single Pulse Shock Tube and ab Initio Study
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   8366 - 8373
Year:   2002
Reference type:   Journal article
Squib:   2002RAJ/RED8366-8373

Reaction:   CH2ClCH2ClCH2=CHCl + HCl
Reaction order:   1
Temperature:   1050 - 1175 K
Pressure:  10.13 - 15.20 bar
Rate expression:   9.55x1013 [±9.0x1013 s-1] e-241835 [±8368 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 8.90E1
1075 1.70E2
1100 3.14E2
1125 5.64E2
1150 9.90E2
1175 1.70E3