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Title: Unimolecular HCl Elimination from 1,2-Dichloroethane: A Single Pulse Shock Tube and ab Initio Study
Journal: J. Phys. Chem. A
Volume: 106
Page(s): 8366 - 8373
Year: 2002
Reference type: Journal article
Squib: 2002RAJ/RED8366-8373
Reaction:
CH2ClCH2Cl → CH2=CHCl + HCl
Reaction order:
1
Temperature:
1050 - 1175
K
Pressure: 10.13 - 15.20 bar
Rate expression:
9.55x1013 [±9.0x1013 s-1] e-241835 [±8368 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1050 | 8.90E1 |
| 1075 | 1.70E2 |
| 1100 | 3.14E2 |
| 1125 | 5.64E2 |
| 1150 | 9.90E2 |
| 1175 | 1.70E3 |