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Author(s):   Sheng, C.Y.; Bozzelli, J.W.; Dean, A.M.; Chang, A.Y.
Title:   Detailed Kinetics and Thermochemistry of C2H5 + O2: Reaction Kinetics of the Chemically-Activated and Stabilized CH3CH2OO. Adduct
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   7276 - 7293
Year:   2002
Reference type:   Journal article
Squib:   2002SHE/BOZ7276-7293

Reaction:   (·)CH2CH2OOH → Oxirane + ·OH
Reaction order:   1
Temperature:   250 - 2500 K
Rate expression:   7.98x1011 [s-1] (T/298 K)0.72 e-64350 [J/mole]/RT
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
250 2.52E-2
300 5.01E0
400 3.90E3
500 2.19E5
600 3.30E6
700 2.33E7
800 1.02E8
900 3.26E8
1000 8.31E8
1100 1.80E9
1200 3.44E9
1300 5.98E9
1400 9.66E9
1500 1.47E10
1600 2.12E10
1700 2.95E10
1800 3.95E10
1900 5.15E10
2000 6.56E10
2100 8.17E10
2200 9.98E10
2300 1.20E11
2400 1.43E11
2500 1.67E11