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Title: Kinetics of the Reaction NH2(X~2B1, v2 = 0 and 1) + NO
Journal: J. Phys. Chem. A
Volume: 106
Page(s): 6563 - 6569
Year: 2002
Reference type: Journal article
Squib: 2002YAM/WAT6563-6569
Reaction:
NH2(X2B1 v2 = 1) + CF4 → NH2(X2B1 v2 = 0) + CF4
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-3 bar
Rate expression:
3.2x10-11 [±5.0x10-12 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
193 nm laser photolysis of NH3 / LIF of v = 0 and v = 1 states, errors are 2 sigma statistical, a bit larger than analgous ND2 rate coefficient previously reported by Chichinin, et al.
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