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Author(s):   Anderson, R.S.; Czuba, E.; Ernst, D.; Huang, L.; Thompson, A.E.; Rudolph, J.
Title:   Method for measuring carbon kinetic isotope effects of gas-phase reactions of light hydrocarbons with the hydroxyl radical
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   6191 - 6199
Year:   2003
Reference type:   Journal article
Squib:   2003AND/CZU6191-6199

Reaction:   1,2-Dimethylbenzene + ·OH → Products
Reaction order:   2
Reference reaction:   Toluene + ·OH → Products
Temperature:   295 K
Pressure:  1.01 bar
Rate expression:   1.14x10-11 [±3.4x10-13 cm3/molecule s]
Bath gas:   air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Sensitized photolysis
Time resolution:   In real time
Analytical technique:   GC-MS
Comments:  
The rate constant of the reference reaction, OH + toluene,
k(OH + toluene) = (5.84 ?0.84)*10-12 cm3molecule-1s-1 was used.

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