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Title: A kinetic and mechanistic study of the gas-phase reactions of OH radicals and Cl atoms with some halogenated acetones and their atmospheric implications
Journal: Phys. Chem. Chem. Phys.
Volume: 5
Page(s): 3874 - 3883
Year: 2003
Reference type: Journal article
Squib: 2003CAR/SHA3874-3883
Reaction:
(CH3)2CO + Cl → Products
Reaction order:
2
Reference reaction:
CH3Cl + Cl → Products
Reference reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
4.42±1.1x10-1
Bath gas:
air
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Sensitized photolysis
Time resolution:
In real time
Analytical technique:
Gas chromatography
Comments:
FTIR was used to identify products.
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