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Author(s):   Gierczak, T.; Gilles, M.K.; Bauerle, S.; Ravishankara, A.R.
Title:   Reaction of hydroxyl radical with acetone. 1. Kinetics of the reactions of OH, OD, and (OH)-O18 with acetone and acetone-d6
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   5014 - 5020
Year:   2003
Reference type:   Journal article
Squib:   2003GIE/GIL5014-5020

Reaction:   (18)OH + (CH3)2CO → Products
Reaction order:   2
Temperature:   296 K
Pressure:  6.67E-2 bar
Rate expression:   1.85x10-13 [±8.0x10-16 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Data obtained between T = 240 K and T = 296 K are also reported.

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