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Title: Alkoxy radicals in the gaseous phase: beta-scission reactions and formation by radical addition to carbonyl compounds
Journal: Can. J. Chem.
Volume: 81
Page(s): 431 - 442
Year: 2003
Reference type: Journal article
Squib: 2003RAU/BOY431-442
Reaction:
(CH3)2CO + ·CH3 → (CH3)3CO
Reaction order:
2
Rate expression:
2.51x10-14 [cm3/molecule s] e-43000 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
Comments:
Rate expression does not contain tunneling contributions. Temperature range not specified but it does include 298.15 K.
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