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Author(s):   Talukdar, R.K.; Gierczak, T.; McCabe, D.C.; Ravishankara, A.R.
Title:   Reaction of hydroxyl radical with acetone. 2. Products and reaction mechanism
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   5021 - 5032
Year:   2003
Reference type:   Journal article
Squib:   2003TAL/GIE5021-5032

Reaction:   (CH3)2CO + ·OHCH3C(O)OH + ·CH3
Reaction order:   2
Reference reaction:   (CH3)2CO + ·OH → Products
Reference reaction order:   2
Temperature:   237 - 353 K
Pressure:  1.47E-3 - 4.27E-3 bar
Rate expression:   1.0x10-2
Rate constant is an upper limit.
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The reported reaction branching ratio was determined by direct measuring of both [OH] and the product concentration.

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