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Title: Reaction of hydroxyl radical with acetone. 2. Products and reaction mechanism
Journal: J. Phys. Chem. A
Volume: 107
Page(s): 5021 - 5032
Year: 2003
Reference type: Journal article
Squib: 2003TAL/GIE5021-5032
Reaction:
(CH3)2CO + ·OH → CH3C(O)CH2(·) + H2O
Reaction order:
2
Reference reaction:
(CH3)2CO + ·OH → Products
Reference reaction order:
2
Temperature:
242 - 353
K
Pressure: 1.47E-3 - 4.27E-3 bar
Rate expression:
9.6x10-1±1.1x10-1
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
The reported reaction branching ratio was determined by direct measuring of both [OH] and the product concentration.
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