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Accessibility information
Author(s):   Urata, S.; Takada, A.; Uchimaru, T.; Chandra, A.K.
Title:   Rate constants estimation for the reaction of hydrofluorocarbons and hydrofluoroethers with OH radicals
Journal:   Chem. Phys. Lett.
Volume:   368
Page(s):   215 - 223
Year:   2003
Reference type:   Journal article
Squib:   2003URA/TAK215-223

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003URA/TAK215-223   CH3CF3 + ·OH → CF3CH2 + H2O  298   3.20E-15           3.20E-15  2
  2003URA/TAK215-223   CH3CF3 + ·OH → CF3CH2 + H2O  298   1.10E-15           1.10E-15  2
  2003URA/TAK215-223   CF3CH2F + ·OH → H2O + CF3CHF  298   5.20E-15           5.20E-15  2
  2003URA/TAK215-223   CF3CH2F + ·OH → H2O + CF3CHF  298   6.00E-15           6.00E-15  2
  2003URA/TAK215-223   C2F5H + ·OH → C2F5 + H2O  298   2.10E-15           2.10E-15  2
  2003URA/TAK215-223   C2F5H + ·OH → C2F5 + H2O  298   1.80E-15           1.80E-15  2
  2003URA/TAK215-223   CH3CHF2 + ·OH → Other Products + H2O  298   8.00E-15           8.00E-15  2
  2003URA/TAK215-223   CHF2CHF2 + ·OH → H2O + CHF2CF2  298   4.80E-15           4.80E-15  2
  2003URA/TAK215-223   CHF2CHF2 + ·OH → H2O + CHF2CF2  298   5.20E-15           5.20E-15  2
  2003URA/TAK215-223   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  298   4.50E-15           4.50E-15  2
  2003URA/TAK215-223   CF3CH2CHF2 + ·OH → Other Products + H2O  298   8.00E-15           8.00E-15  2
  2003URA/TAK215-223   CF3CH2CHF2 + ·OH → Other Products + H2O  298   1.03E-14           1.03E-14  2
  2003URA/TAK215-223   CF3CH2CH2CF3 + ·OH → CF3CH2CH(·)CF3 + H2O  298   7.40E-15           7.40E-15  2
  2003URA/TAK215-223   CF3CH2CH2CF3 + ·OH → CF3CH2CH(·)CF3 + H2O  298   5.80E-15           5.80E-15  2
  2003URA/TAK215-223   CF3CH2CF2CH3 + ·OH → Other Products + H2O  298   6.20E-15           6.20E-15  2
  2003URA/TAK215-223   CF3CH2CF2CH3 + ·OH → Other Products + H2O  298   3.10E-15           3.10E-15  2
  2003URA/TAK215-223   (CH3)2O + ·OH → H2O + CH3OCH2  298   2.73E-12           2.73E-12  2
  2003URA/TAK215-223   (CH3)2O + ·OH → H2O + CH3OCH2  298   6.49E-13           6.49E-13  2
  2003URA/TAK215-223   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298   2.68E-14           2.68E-14  2
  2003URA/TAK215-223   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298   1.00E-15           1.00E-15  2
  2003URA/TAK215-223   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298   1.70E-15           1.70E-15  2
  2003URA/TAK215-223   ·OH + Pentafluorodimethyl ether → H2O + CF3OCF2(·)  298   3.00E-16           3.00E-16  2
  2003URA/TAK215-223   ·OH + Pentafluorodimethyl ether → H2O + CF3OCF2(·)  298   5.00E-16           5.00E-16  2
  2003URA/TAK215-223   CH3OCF2CHF2 + ·OH → Other Products + H2O  298   1.80E-14           1.80E-14  2
  2003URA/TAK215-223   CH3OCF2CHF2 + ·OH → Other Products + H2O  298   1.50E-14           1.50E-14  2
  2003URA/TAK215-223   CF3CH2OCHF2 + ·OH → Other Products + H2O  298   9.86E-14           9.86E-14  2
  2003URA/TAK215-223   CF3CH2OCHF2 + ·OH → Other Products + H2O  298   4.36E-14           4.36E-14  2
  2003URA/TAK215-223   CH3OCF2CF3 + ·OH → ·CH2OCF2CF3 + H2O  298   1.56E-14           1.56E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH3 + ·OH → Other Products + H2O  298   1.77E-14           1.77E-14  2
  2003URA/TAK215-223   CH3OCF2CF3 + ·OH → ·CH2OCF2CF3 + H2O  298   1.26E-14           1.26E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH3 + ·OH → Other Products + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CF3CH2OCH2CF3 + ·OH → CF3CH(.)OCH2CF3 + H2O  298   1.54E-13           1.54E-13  2
  2003URA/TAK215-223   CF3CH2OCH2CF3 + ·OH → CF3CH(.)OCH2CF3 + H2O  298   4.55E-13           4.55E-13  2
  2003URA/TAK215-223   CF3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.61E-14           1.61E-14  2
  2003URA/TAK215-223   CH3OCF2CF2CF3 + ·OH → CF3CF2CF2OCH2 + H2O  298   1.54E-14           1.54E-14  2
  2003URA/TAK215-223   CF3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.26E-14           1.26E-14  2
  2003URA/TAK215-223   CH3OCF2CF2CF3 + ·OH → CF3CF2CF2OCH2 + H2O  298   1.25E-14           1.25E-14  2
  2003URA/TAK215-223   CHF2OCH2CF2CF3 + ·OH → Other Products + H2O  298   6.48E-14           6.48E-14  2
  2003URA/TAK215-223   CH3OCF(CF3)2 + ·OH → CF3CF2CF2OCH2 + H2O  298   5.40E-15           5.40E-15  2
  2003URA/TAK215-223   CH3OCF(CF3)2 + ·OH → CF3CF2CF2OCH2 + H2O  298   5.90E-15           5.90E-15  2
  2003URA/TAK215-223   CHF2OCH2CF2CF3 + ·OH → Other Products + H2O  298   1.74E-13           1.74E-13  2
  2003URA/TAK215-223   C2H5F + ·OH → Other Products + H2O  298   1.83E-14           1.83E-14  2
  2003URA/TAK215-223   C2H5F + ·OH → Other Products + H2O  298   4.28E-14           4.28E-14  2
  2003URA/TAK215-223   CH2FCHF2 + ·OH → Other Products + H2O  298   9.50E-15           9.50E-15  2
  2003URA/TAK215-223   CH2FCHF2 + ·OH → Other Products + H2O  298   1.40E-14           1.40E-14  2
  2003URA/TAK215-223   CH3CH2CF3 + ·OH → Other Products + H2O  298   1.38E-14           1.38E-14  2
  2003URA/TAK215-223   CH3CH2CF3 + ·OH → Other Products + H2O  298   3.21E-14           3.21E-14  2
  2003URA/TAK215-223   CF3CHFCH2F + ·OH → Other Products + H2O  298   2.02E-14           2.02E-14  2
  2003URA/TAK215-223   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  298   6.70E-15           6.70E-15  2
  2003URA/TAK215-223   ·OH + CHF2CHFCHF2 → Other Products + H2O  298   2.05E-14           2.05E-14  2
  2003URA/TAK215-223   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  298   6.50E-15           6.50E-15  2
  2003URA/TAK215-223   CF3CHFCH2F + ·OH → Other Products + H2O  298   1.01E-14           1.01E-14  2
  2003URA/TAK215-223   Propane, 1,1,1,2,2,3-hexafluoro- + ·OH → CF3CF2CHF· + H2O  298   4.00E-15           4.00E-15  2
  2003URA/TAK215-223   ·OH + CHF2CHFCHF2 → Other Products + H2O  298   1.02E-14           1.02E-14  2
  2003URA/TAK215-223   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298   6.40E-15           6.40E-15  2
  2003URA/TAK215-223   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298   3.60E-15           3.60E-15  2
  2003URA/TAK215-223   Propane, 1,1,1,2,2,3-hexafluoro- + ·OH → CF3CF2CHF· + H2O  298   3.30E-15           3.30E-15  2
  2003URA/TAK215-223   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298   2.60E-15           2.60E-15  2
  2003URA/TAK215-223   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298   1.07E-14           1.07E-14  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2F → Other Products + H2O  298   1.13E-14           1.13E-14  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2F → Other Products + H2O  298   1.82E-14           1.82E-14  2
  2003URA/TAK215-223   CHF2CF2CF2CHF2 + ·OH → CHF2CF2CF2CF2· + H2O  298   4.40E-15           4.40E-15  2
  2003URA/TAK215-223   CHF2CF2CF2CHF2 + ·OH → CHF2CF2CF2CF2· + H2O  298   4.30E-15           4.30E-15  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2CF2CF3 → CF3CF2CH2CH(.)CF2CF3 + H2O  298   5.60E-15           5.60E-15  2
  2003URA/TAK215-223   ·OH + CF3CH2CF2CH2CF3 → CF3CH2CF2CH(.)CF3 + H2O  298   7.00E-15           7.00E-15  2
  2003URA/TAK215-223   ·OH + CF3CH2CF2CH2CF3 → CF3CH2CF2CH(.)CF3 + H2O  298   4.90E-15           4.90E-15  2
  2003URA/TAK215-223   ·OH + CF3CHFCHFCF2CF3 → Other Products + H2O  298   6.30E-15           6.30E-15  2
  2003URA/TAK215-223   CF3CH2OCH3 + ·OH → Other Products + H2O  298   1.27E-12           1.27E-12  2
  2003URA/TAK215-223   ·OH + CF3CHFCHFCF2CF3 → Other Products + H2O  298   1.06E-14           1.06E-14  2
  2003URA/TAK215-223   CH3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.72E-13           1.72E-13  2
  2003URA/TAK215-223   CH3CH2OCF2CF2H + ·OH → Other Products + H2O  298   6.69E-14           6.69E-14  2
  2003URA/TAK215-223   CHF2OCH2CF2CHF2 + ·OH → Other Products + H2O  298   1.70E-13           1.70E-13  2
  2003URA/TAK215-223   CHF2OCH2CF2CHF2 + ·OH → Other Products + H2O  298   6.62E-14           6.62E-14  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2CF2CF3 → CF3CF2CH2CH(.)CF2CF3 + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   1.66E-13           1.66E-13  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   6.31E-14           6.31E-14  2
  2003URA/TAK215-223   CF3CH2OCH3 + ·OH → Other Products + H2O  298   3.25E-13           3.25E-13  2
  2003URA/TAK215-223   CH3OCHF2 + ·OH → Other Products + H2O  298   5.96E-14           5.96E-14  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   6.31E-14           6.31E-14  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   1.66E-13           1.66E-13  2
  2003URA/TAK215-223   ·OH + HCF2OCF2CF2OCF2H → CHF2OCF2CF2OCF2 + H2O  298   8.00E-16           8.00E-16  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → CH2OC4F9 + H2O  298   1.53E-14           1.53E-14  2
  2003URA/TAK215-223   ·OH + HCF2OCF2CF2OCF2H → CHF2OCF2CF2OCF2 + H2O  298   1.40E-15           1.40E-15  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → CH2OC4F9 + H2O  298   1.24E-14           1.24E-14  2
  2003URA/TAK215-223   CH2FCH2OH + ·OH → Other Products + H2O  298   1.92E-13           1.92E-13  2
  2003URA/TAK215-223   CHF2CH2OCF3 + ·OH → Other Products + H2O  298   3.27E-14           3.27E-14  2
  2003URA/TAK215-223   CH2FCF2OCHF2 + ·OH → Other Products + H2O  298   6.50E-15           6.50E-15  2
  2003URA/TAK215-223   CF3CH(OH)CF3 + ·OH → CF3CHOCF3 + H2O  298   1.49E-14           1.49E-14  2
  2003URA/TAK215-223   CF3CF2CH2OCF3 + ·OH → CF3CF2CH(.)OCF3 + H2O  298   1.03E-14           1.03E-14  2
  2003URA/TAK215-223   CF3CH(OH)CF3 + ·OH → Other Products + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·OH → H2O + CF3OCF2CF2·  298   2.30E-15           2.30E-15  2
  2003URA/TAK215-223   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·OH → CF3CF(.)OCF3 + H2O  298   1.30E-15           1.30E-15  2
  2003URA/TAK215-223   CHF2CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.92E-13           3.92E-13  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → Other Products + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CF3CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.94E-13           3.94E-13  2
  2003URA/TAK215-223   CHF2CF2CF2OCH3 + ·OH → Other Products + H2O  298   1.55E-14           1.55E-14  2
  2003URA/TAK215-223   CF3CF2CH2OCF3 + ·OH → CF3CF2CH(.)OCF3 + H2O  298   2.36E-14           2.36E-14  2
  2003URA/TAK215-223   ·OH + CF3CHFCF2OCH2CF2CHF2 → Other Products + H2O  298   2.40E-14           2.40E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   2.12E-14           2.12E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   6.82E-14           6.82E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   1.53E-14           1.53E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → Other Products + H2O  298   1.54E-14           1.54E-14  2
  2003URA/TAK215-223   CHF2CF2CF2CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.83E-13           3.83E-13  2
  2003URA/TAK215-223   CH3CHF2 + ·OH → Other Products + H2O  298   8.50E-15           8.50E-15  2
Search returned 106 records.