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Author(s):   Wu, H.; Mu, Y.; Zhang, X.; Jiang, G.
Title:   Relative Rate Constants for the Reactions of Hydroxyl Radicals and Chlorine Atoms with a Series of Aliphatic Alcohols
Journal:   Int. J. Chem. Kinet.
Volume:   35
Page(s):   81 - 87
Year:   2003
Reference type:   Journal article
Squib:   2003WU/MU81-87

Reaction:   C2H5OH + Cl → Products
Reaction order:   2
Reference reaction:   C3H8 + Cl → Products
Temperature:   295 K
Pressure:  1.01 bar
Rate expression:   1.03x10-10 [±4.0x10-12 cm3/molecule s]
Bath gas:   air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   The rate constants derived in this paper are based on the following rate constants for the reference reactions:

k(OH+propane)=1.08

k(OH+cyclohexane)=7.22

k(Cl+propane)=131

k(Cl+ cyclohexane) = 307

(units are 10-12 cm3 molecule-1s-1)

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