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Title: Carbon kinetic isotope effects in the gas phase reactions of light alkanes and ethene with the OH radical at 29±
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 11537 - 11544
Year: 2004
Reference type: Journal article
Squib: 2004AND/HUA11537-11544
Reaction:
n-C4H10 + ·OH → Products
Reaction order:
2
Temperature:
296
K
Pressure: 1.01 bar
Rate expression:
2.5x10-12 [±6.0x10-13 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
GC-MS
Comments:
Carbon-13 kinetic isotope effects were also determined.
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