Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Becerra, R.; Goldberg, N.; Cannady, J.P.; Almond, M.J.; Ogden, J.S.; Walsh, R.
Title:   Experimental and theoretical evidence for homogeneous catalysis in the gas-phase reaction of SiH2 with H2O (and D2O): A combined kinetic and quantum chemical study
Journal:   J. Am. Chem. Soc.
Volume:   126
Page(s):   6816 - 6824
Year:   2004
Reference type:   Journal article
Squib:   2004BEC/GOL6816-6824

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2004BEC/GOL6816-6824   H2O + H2O + SiH2 → H2O + SiH3OH  297   3.80E-51              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2 → H2O + SiH3OH  345   6.80E-31              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  297   2.18E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  345   5.40E-31              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2 → H2O + SiH3OH  297   6.00E-30              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2 → H2O + SiH3OH  345   2.95E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  297   5.40E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  345   2.20E-30              3
Search returned 8 records.