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Title: Matrix isolation infrared spectroscopic and density functional theoretical studies of the reactions of scandium atoms with methanol
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 5950 - 5955
Year: 2004
Reference type: Journal article
Squib: 2004CHE/HUA5950-5955
Reaction:
CH3OH + Sc → CH3OSc + H·
Reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Other
Excitation technique:
Thermal
Analytical technique:
IR absorption
Comments:
1) Reaction was not confirmed. Alternate reaction is also proposed to account for the CH3OSc product.
2) This reaction product was not observed. CH3OScH is the main product. The reactions of scandium atoms and methanol molecules were investigated by matrix isolation infrared absorption spectroscopy. Scandium atoms were produced with laser ablation and co-deposited with methanol in an argon cryogenic matrix. The products were observed to increase as the matrix was annealed.
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