Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Cuevas, C.A.; Notario, A.; Martinez, E.; Albaladejo, J.
Title:   A kinetic study of the reaction of Cl with a series of linear and ramified ketones as a function of temperature
Journal:   Phys. Chem. Chem. Phys.
Volume:   6
Page(s):   2230 - 2236
Year:   2004
Reference type:   Journal article
Squib:   2004CUE/NOT2230-2236

Reaction:   C2H5COCH3 + Cl → Products
Reaction order:   2
Temperature:   266 - 380 K
Pressure:  2.67E-2 - 0.40 bar
Rate expression:   7.3x10-11 [±1.24x10-11 cm3/molecule s] e-1987 [±898 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
266 2.97E-11
275 3.06E-11
300 3.29E-11
325 3.50E-11
350 3.69E-11
375 3.86E-11
380 3.89E-11