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Author(s):   Cuevas, C.A.; Notario, A.; Martinez, E.; Albaladejo, J.
Title:   A kinetic study of the reaction of Cl with a series of linear and ramified ketones as a function of temperature
Journal:   Phys. Chem. Chem. Phys.
Volume:   6
Page(s):   2230 - 2236
Year:   2004
Reference type:   Journal article
Squib:   2004CUE/NOT2230-2236

Reaction:   C2H5COCH3 + ·Cl → Products
Reaction order:   2
Temperature:   266 - 380 K
Pressure:  2.67E-2 - 0.40 bar
Rate expression:   7.3x10-11 [±1.24x10-11 cm3/molecule s] e-1987 [±898 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
266 2.97E-11
275 3.06E-11
300 3.29E-11
325 3.50E-11
350 3.69E-11
375 3.86E-11
380 3.89E-11