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Title: Kinetic studies of the reactions of O(1D) with several atmospheric molecules
Journal: Phys. Chem. Chem. Phys.
Volume: 6
Page(s): 2152 - 2161
Year: 2004
Reference type: Journal article
Squib: 2004DUN/RAV2152-2161
Reaction:
O(1D) + CO2 → O(3P) + CO2
Reaction order:
2
Temperature:
220 - 370
K
Pressure: 2.40E-2 - 4.40E-2 bar
Rate expression:
7.9x10-11 [±7.0x10-12 cm3/molecule s] e915 [±166 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Resonance fluorescence
Comments:
Reported uncertainties are at the 95% confidence level and include estimates of systematic errors.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 220 | 1.30E-10 |
| 225 | 1.29E-10 |
| 250 | 1.23E-10 |
| 275 | 1.18E-10 |
| 300 | 1.14E-10 |
| 325 | 1.11E-10 |
| 350 | 1.08E-10 |
| 370 | 1.06E-10 |