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Title: Kinetics of C2(a3Piu) radical reactions with alkanes by LIF
Journal: J. Chem. Phys.
Volume: 120
Page(s): 2225 - 2229
Year: 2004
Reference type: Journal article
Squib: 2004HUA/ZHU2225-2229
Reaction:
C2(a3PIu) + n-C4H10 → Products
Reaction order:
2
Temperature:
298
K
Pressure: 8.67E-3 bar
Rate expression:
3.19x10-11 [±1.5x10-12 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Reaction mechanism is likely to be that of hydrogen abstraction. Reported uncertainty is 1 sigma.
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