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Title: Atmospheric chemistry of fluorinated alcohols: Reaction with Cl atoms and OH radicals and atmospheric lifetimes
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 1973 - 1979
Year: 2004
Reference type: Journal article
Squib: 2004HUR/WAL1973-1979
Reaction:
CF3CF2CF2CH2OH + Cl → Products
Reaction order:
2
Reference reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
6.48x10-13±5.3x10-14
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
Reported uncertainties are 2 sigma and are precision only. Reported rate constant is average of relative rates normalized to Cl+CH3Cl (4.8e-13 cm3 molecule-1 s-1) and Cl + CH3OC(O)H (1.4e-12 cm3 molecule-1 s-1).
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