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Accessibility information
Author(s):   Oehlschlaeger, M.A.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   4247 - 4253
Year:   2004
Reference type:   Journal article
Squib:   2004OEH/DAV4247-4253

Reaction:   n-C4H10n-C3H7 + ·CH3
Reaction order:   1
Temperature:   1320 - 1600 K
Rate expression:   4.28x1014 [s-1] e-292503 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit
Comments:   RRKM-Master Equation model created on the basis of experimental data obtained in shock tube experiments in the same work.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1320 1.14E3
1325 1.26E3
1350 2.06E3
1375 3.31E3
1400 5.23E3
1425 8.12E3
1450 1.24E4
1475 1.88E4
1500 2.79E4
1525 4.10E4
1550 5.95E4
1575 8.53E4
1600 1.21E5