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Accessibility information
Author(s):   Oehlschlaeger, M.A.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   4247 - 4253
Year:   2004
Reference type:   Journal article
Squib:   2004OEH/DAV4247-4253

Reaction:   n-C4H10·C2H5 + ·C2H5
Reaction order:   1
Temperature:   1320 - 1600 K
Rate expression:   2.72x1015 [s-1] e-316366 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit
Comments:   RRKM-Master Equation model created on the basis of experimental data obtained in shock tube experiments in the same work.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1320 8.24E2
1325 9.18E2
1350 1.56E3
1375 2.61E3
1400 4.28E3
1425 6.89E3
1450 1.09E4
1475 1.70E4
1500 2.62E4
1525 3.97E4
1550 5.93E4
1575 8.76E4
1600 1.28E5