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Title: Kinetic study for the reactions of several hydrofluoroethers with chlorine atoms
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 2666 - 2674
Year: 2004
Reference type: Journal article
Squib: 2004PAP/KAM2666-2674
Reaction:
CH3OCF2CHF2 + Cl → Products
Reaction order:
2
Temperature:
273 - 363
K
Rate expression:
5.49x10-12 [±1.51x10-12 cm3/molecule s] e-7716 [±1289 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Very low pressure cells (VLPP,Knudsen)
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
Uncertainties in the Arrhenius parameters are 2 sigma.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 273 | 1.83E-13 |
| 275 | 1.88E-13 |
| 300 | 2.49E-13 |
| 325 | 3.16E-13 |
| 350 | 3.87E-13 |
| 363 | 4.26E-13 |