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Title: Recombination versus disproportionation reactions of hydrogen atoms with ClCF2CHF, ClC2F4, BrC2H4, BrC2F4, and BrCF2CFBr radicals and unimolecular reactions of the haloethane molecules from recombination
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 3745 - 3755
Year: 2004
Reference type: Journal article
Squib: 2004SET/MUR3745-3755
Reaction:
H· + CF2BrCF2 → Other Products + HF + HBr
Reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Chemiluminescence
Comments:
1,1 elimination mostly, HBr/HF = 2.7 (+/-1.0)
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