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Title: Temperature dependence of the alpha-ester rearrangement reaction
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 6850 - 6856
Year: 2004
Reference type: Journal article
Squib: 2004TYN/PIM6850-6856
Reaction:
CH3C(O)OCH2O → CH3C(O)OH + HCO
Reaction order:
1
Temperature:
298
K
Pressure: 2.03 bar
Rate expression:
4.2x1012 [s-1] e-42258 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Mechanistic study of the alpha ester rearrangement process using competitive reaction with O2 and RT information on OH reactions.
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