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Title: Absolute determinations of the addition rate constants for the reactions of O(3P) atoms with halogenated propenes and butenes. A structure-activity relationship for the estimation of rate constants
Journal: J. Phys. Org. Chem.
Volume: 18
Page(s): 142 - 147
Year: 2005
Reference type: Journal article
Squib: 2005COM/TER142-147
Reaction:
O(3P) + CH2=CCl2 → Products
Reaction order:
2
Temperature:
298
K
Rate expression:
2.9x10-13 [cm3/molecule s]
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
Comments:
Theoretical rate coefficient estimated using structureactivity relationships (SAR) for O(3P) atom addition to alkenes based on the approach developed by Atkinson (Atkinson R., Chem. Rev. 1986; 86: 69201.) for OH radical reactions.
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