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Author(s):   Dils, B.; Vertommen, J.; Carl, S.A.; Vereecken, L.; Peeters, J.
Title:   The kinetics of the CF3+CF3 and CF3+F combination reactions at 290 K and at He-pressures of approximate to 1-6 Torr
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   1187 - 1193
Year:   2005
Reference type:   Journal article
Squib:   2005DIL/VER1187-1193

Reaction:   ·CF3 + ·FCF4
Reaction order:   3
Temperature:   290 K
Pressure:  6.67E-4 - 8.00E-3 bar
Rate expression:   1.47x10-28 [±2.4x10-29 cm6/molecule2 s]
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry

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