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Title: The kinetics of the CF3+CF3 and CF3+F combination reactions at 290 K and at He-pressures of approximate to 1-6 Torr
Journal: Phys. Chem. Chem. Phys.
Volume: 7
Page(s): 1187 - 1193
Year: 2005
Reference type: Journal article
Squib: 2005DIL/VER1187-1193
Reaction:
·CF3 + ·F → CF4
Reaction order:
3
Temperature:
290
K
Pressure: 6.67E-4 - 8.00E-3 bar
Rate expression:
1.47x10-28 [±2.4x10-29 cm6/molecule2 s]
Category: Experiment
Data type:
High or low pressure extrapolation
Pressure dependence:
Rate constant is low pressure limit
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
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