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Author(s):   Enami, S.; Hashimoto, S.; Kawasaki, M.; Nakano, Y.; Ishiwata, T.; Tonokura, K.; Wallington, T.J.
Title:   Observation of adducts in the reaction of Cl atoms with XCH2I (X = H, CH3, Cl, Br, I) using cavity ring-down spectroscopy
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   1587 - 1593
Year:   2005
Reference type:   Journal article
Squib:   2005ENA/HAS1587-1593

Reaction:   CH3Br + Cl → Adduct
Reaction order:   2
Temperature:   218 - 250 K
Pressure:  0.13 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (Vis-UV)
Comments:   Cl atoms generated by laser photolysis of Cl2 and adduct formation sought by cavity ring-down spectroscopy. No adduct formation observed.

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