Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Near-IR cavity ringdown spectroscopy and kinetics of the isomers and conformers of the butyl peroxy radical
Journal: J. Phys. Chem. A
Volume: 109
Page(s): 11191 - 11197
Year: 2005
Reference type: Journal article
Squib: 2005GLO/MIL11191-11197
Reaction:
n-C4H10 + Cl → sec-C4H9 + HCl
Reaction order:
2
Reference reaction:
n-C4H10 + Cl → n-C4H9 + HCl
Reference reaction order:
2
Temperature:
298
K
Pressure: 0.31 bar
Rate expression:
4.5
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
193-nm photolysis of (COCl)2 used as source of Cl atoms.
Yield of specific butyl radicals based on isomer specific yields of butyl peroxul radicals determined by cavity ringdown spectroscopy.
View full bibliographic record.