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Title: The hydrogen kinetic isotope effects of the reactions of n-alkanes with chlorine atoms in the gas phase
Journal: J. Atmos. Chem.
Volume: 50
Page(s): 121 - 138
Year: 2005
Reference type: Journal article
Squib: 2005IAN/AND121-138
Reaction:
n-hexane-d1 + Cl → Products + DCl
Reaction order:
2
Reference reaction:
n-C6H14 + Cl → Products + HCl
Reference reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
9.76x10-1±1.0x10-3
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
GC-MS
Comments:
The time dependence of the isotope ratio followed during photolysis of Cl2 in the presence of natural-abundance alkane. Gas chromatography pyrolysis isotome ratio mass spectrometry was utilized.
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