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Author(s):   Johnson, D.; Carr, S.; Cox, R.A.
Title:   The kinetics of the gas-phase decomposition of the 2-methyl-2-butoxyl and 2-methyl-2-pentoxyl radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   2182 - 2190
Year:   2005
Reference type:   Journal article
Squib:   2005JOH/CAR2182-2190

Reaction:   CH3CH2C(CH3)2O(·) → (CH3)2CO + ·C2H5
Reaction order:   1
Reference reaction:   CH3CH2C(CH3)2O(·) → C2H5COCH3 + ·CH3
Reference reaction order:   1
Temperature:   283 - 345 K
Pressure:  1.01 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Ratios of rate constants were obtained at individual temperatures and reported in a tabular form. No Arrhenius expression was reported. The rate constants ratio at 2982 K is 48.7 +/- 6.9 (2 sigma).

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