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Title: Kinetic study of the gas-phase reaction of atomic chlorine with a series of aldehydes
Journal: Atmos. Chem. Phys.
Volume: 5
Page(s): 3433 - 3440
Year: 2005
Reference type: Journal article
Squib: 2005ROD/ROD3433-3440
Reaction:
n-C5H11CHO + Cl → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
2.88x10-10 [±3.7x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Both air and N2 used as bath gases. Absolute rate constant based on relative rate measurements with ethane, propene, and 1-butene.
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