Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Taketani, F.; Nakayama, T.; Takahashi, K.; Matsumi, Y.; Hurley, M.D.; Wallington, T.J.; Toft, A.; Andersen, M.PS.
Title:   Atmospheric chemistry of CH3CHF2 (HFC-152a): Kinetics, mechanisms, and products of Cl atom- and OH radical-initiated oxidation in the presence and absence of NOx
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   9061 - 9069
Year:   2005
Reference type:   Journal article
Squib:   2005TAK/NAK9061-9069

Reaction:   CH3CHF2 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl → Products
Reference reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   2.39±1.5x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Cl-atoms generated by the uv photolysis of Cl2.

View full bibliographic record.