Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Vasudevan, V.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature measurements of the reactions of OH with toluene and acetone
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3352 - 3359
Year:   2005
Reference type:   Journal article
Squib:   2005VAS/DAV3352-3359

Reaction:   Toluene + ·OH → Products
Reaction order:   2
Temperature:   911 - 1389 K
Pressure:  2.10 - 2.86 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   No Arrhenius expression is given for the experimental k(T) dependence. Instead, rate constants for individual temperatures are presented in a tabular format.

View full bibliographic record.