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Accessibility information
Author(s):   Vasudevan, V.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature measurements of the reactions of OH with toluene and acetone
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3352 - 3359
Year:   2005
Reference type:   Journal article
Squib:   2005VAS/DAV3352-3359

Reaction:   Toluene + ·OH → Products
Reaction order:   2
Temperature:   570 - 1389 K
Rate expression:   2.69x10-11 [cm3/molecule s] e-11590 [J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Arrhenius expression is derived from a combination of the experimental data of the current work and those of an earlier study.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
570 2.33E-12
600 2.63E-12
650 3.15E-12
700 3.67E-12
750 4.19E-12
800 4.71E-12
850 5.22E-12
900 5.72E-12
950 6.20E-12
1000 6.67E-12
1050 7.13E-12
1100 7.58E-12
1150 8.00E-12
1200 8.42E-12
1250 8.82E-12
1300 9.21E-12
1350 9.58E-12
1389 9.86E-12