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Accessibility information
Author(s):   Yu, H.; Kennedy, E.M.; Uddin, A.; Sullivan, S.P.; Dlugogorski, B.Z.
Title:   Experimental and computational studies of the thermal decomposition of Halon 1211
Journal:   Inter. J. Chem. Kinet.
Volume:   37
Page(s):   134 - 146
Year:   2005
Reference type:   Journal article
Squib:   2005YU/KEN134-146

Reaction:   CF2BrCl + ·CClF2CF2Cl2 + CBrF2
Reaction order:   2
Temperature:   773 - 1073 K
Rate expression:   3.16x10-13 [cm3/molecule s] e-43110 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Comments:   Derived from modeling experimental results on thermal pyrolysis of CCBrClF2.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
773 3.85E-16
775 3.92E-16
800 4.83E-16
825 5.88E-16
850 7.08E-16
875 8.42E-16
900 9.93E-16
925 1.16E-15
950 1.34E-15
975 1.55E-15
1000 1.77E-15
1025 2.01E-15
1050 2.26E-15
1073 2.51E-15