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Home ©NIST, 2013 Accessibility information |
Title: Falloff curves for the recombination reaction Cl+FC(O)O+M -> FC(O)OCl+M
Journal: J. Phys. Chem. A
Volume: 110
Page(s): 3186 - 3196
Year: 2006
Reference type: Journal article
Squib: 2006BAD/CRO3186-3196
Reaction:
Cl + FC(O)O· → FC(O)OCl
Reaction order:
3
Temperature:
296
K
Pressure: 3.37E-2 - 0.82 bar
Rate expression:
2.2x10-28 [±4.0x10-29 cm6/molecule2 s]
Category: Experiment
Data type:
High or low pressure extrapolation
Pressure dependence:
Rate constant is low pressure limit
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
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