Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Chen, W.C.;Marcus, R.A.
Title:   On the theory of the reaction rate of vibrationally excited CO molecules with OH radicals
Journal:   J. Chem. Phys.
Volume:   124
Page(s):  
Year:   2006
Reference type:   Journal article
Squib:   2006CHE/MAR24306

Reaction:   CO(«nu»=3) + ·OHCO2 +
Reaction order:   2
Rate expression:   1.21x10-13 [cm3/molecule s]
Category:  Experiment
Data type:   RRK(M) extrapolation
Comments:   Rate constant for the vibrationally-specific reaction derived from a non-statistical RRKM analysis using a previously-calculated potential energy surface. The intramolecular energy transfer between the hi-frequency OH-stretching modes and the other lower-frequency modes is not rapid enough.

View full bibliographic record.