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Author(s):   Christensen, L.E.; Okumura, M.; Hansen, J.C.; Sander, S.P.
Title:   Experimental and ab initio study of the HO2 center dot CH3OH complex: Thermodynamics and kinetics of formation
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   6948 - 6959
Year:   2006
Reference type:   Journal article
Squib:   2006CHR/OKU6948-6959

Reaction:   HO2-CH3OH complex → CH3OH + HO2
Reaction order:   2
Temperature:   231 - 261 K
Pressure:  6.67E-2 - 0.13 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Rate constants were determined at individual temperatures and presented in tabular format. No Arrhenius expression is given. Equilibrium constants were determined by monitoring relaxation to equilibrium.

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