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Title: Unimolecular dissociation of the CH3OCO radical: An intermediate in the CH3O+COreaction
Journal: J. Phys. Chem. A
Volume: 110
Page(s): 1625 - 1634
Year: 2006
Reference type: Journal article
Squib: 2006MCC/LAU1625-1634
Reaction:
CH3OC(·)(O) → CO2 + ·CH3
Reaction order:
1
Reference reaction:
CH3OC(·)(O) → Products
Reference reaction order:
1
Rate expression:
no rate data available
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
Branching in decomposition of highly vibrationally excited CH3OCO was studied. No thermal rate constants or branching fractions were obtained.
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