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Author(s):   McCunn, L.R.; Lau, K.C.; Krisch, M.J.; Butler, L.J.; Tsung, J.W.; Lin, J.J.
Title:   Unimolecular dissociation of the CH3OCO radical: An intermediate in the CH3O+COreaction
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   1625 - 1634
Year:   2006
Reference type:   Journal article
Squib:   2006MCC/LAU1625-1634

Reaction:   CH3OC(·)(O) → CO2 + ·CH3
Reaction order:   1
Reference reaction:   CH3OC(·)(O) → Products
Reference reaction order:   1
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Comments:   Reaction potential energy surface was studied using quantum chemistry and product branching fractions in decomposition of highly vibrationally excited CH3OCO were calculated using RRKM. No thermal rate constants or branching fractions were obtained.

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