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Author(s):   Monsalve, A.; Rosas, F.; Tosta, M.; Herize, A.; Dominguez, R.M.; Brusco, D.; Chuchani, G.
Title:   The elimination kinetics and mechanisms of ethyl piperidiner-3-carboxylate, ethyl 1-methylpiperidine-3-carboxylate, and ethyl 3-(piperidin-1-yl) propionate in the gas phase
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   106 - 114
Year:   2006
Reference type:   Journal article
Squib:   2006MON/ROS106-114

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006MON/ROS106-114   1-Piperidinepropanoic acid, ethyl ester → C2H4 + CO2 + Piperidine, 1-ethyl-  642 - 694   6.17E12       2.00E05      1
  2006MON/ROS106-114   Ethyl 1-methylnipecotate → C2H4 + CO2 + N-Methylpiperidine  684 - 723   1.17E13       2.13E05      1
  2006MON/ROS106-114   Ethyl piperidine-3-carboxylate → C2H4 + 3-Piperidine Carboxylic Acid  665 - 704   1.32E13       2.10E05      1
  2006MON/ROS106-114   3-Piperidine Carboxylic Acid → Piperidine + CO2  665 - 704   1.74E14       2.34E05      1
Search returned 4 records.